Edible Water Balloons (and popping boba)

 - by KitchenPantryScientist

Sodium alginate (Say it like you say algae!) is a substance found in the cell walls of brown algae, including seaweeds and kelp. Its rubbery, gel-like consistency may be important for the flexibility of seaweed, which gets tossed around on ocean waves.

Edible Water Balloons- KitchenPantryScientist.com

Edible Water Balloons- KitchenPantryScientist.com

Here on dry land, you can use sodium alginate to make edible balloon-like blobs that are liquid in the middle. We can thank scientists for this delicious project, since they discovered that a chemical reaction between sodium alginate and calcium causes the alginate to polymerize, or form a gel. In this experiment, the gel forms on the outside of a sodium alginate blob, where the chemical reaction is taking place. The inside of the blob remains liquid!

No heat is required for this experiment, making it safe and fun for all ages!

Sodium alginate and calcium lactate can be tricky to find at the grocery store, so you’ll probably have to order them online. But they’re not very expensive, and you’ll have lots of fun playing with them!

You’ll need:

-a blender or hand blender (parental supervision required for small children)

-1/2 tsp sodium alginate

-2 tsp calcium lactate

-flavored drink drops, like Kool-Aid or Tang (optional)

-water

-a spoon

-squeeze bottle or syringe for popping boba*

You can make these with juice, but if there is any calcium in the juice, you may end up with foam in your blender, since it may start to polymerize the sodium alginate when you blend it in. 

  1. Add 1 and 1/2 cup water (or calcium-free juice) to the blender.
  2. To the water, add 1/2 tsp. sodium alginate.
  3. Blend for about a minute, and let rest for 15 or 20 minutes, or until the bubbles are gone.
  4. If you want to add flavor, divide the sodium alginate solution into small containers and stir in the flavor, like a squirt of Kool-Aid liquid.

    Add liquid drink drops to add flavor and color (KitchenPantryScientist.com)

    Add liquid drink drops to add flavor and color (KitchenPantryScientist.com)

  5. Add 4 cups of water to a clean, clear glass bowl or container.
  6. To the water, add 2 tsp. calcium lactate and mix until completely dissolved. This is your calcium lactate “bath.”
  7. To make edible water balloons, fill a spoon, like a tablespoon, with the sodium alginate solution, and slowly lower it down into the calcium lactate bath. You’ll see a gel begin to form. Gently turn the spoon so the sodium alginate falls off the spoon and into the calcium lactate.

    Gently turn the spoon upside down.

    Gently turn the spoon upside down.

  8. After about 30 seconds, you’ll be able to see a pale blob in the water. Leave it there for three or four minutes. You can make several edible balloons at once.

    IMG_5400

    After a few minutes, you’ll see a pale blob.

  9. When the blobs are ready, use a spoon to carefully remove them from the bath and put them in a clean bowl of water for a few seconds to rinse them off.

    Rinse balloons off in water.

    Rinse balloons off in water.

  10. Put your edible balloons on a plate and taste them. What do you think?
  11. *To make popping boba, add the fruit-flavored sodium alginate to a squeeze bottle or syringe. Drip the flavored sodium alginate into the calcium lactate as fairly large drops. It may take some practice to get uniform drops of the size you desire. When they’re solid enough to remove from the calcium lactate, rinse them gently and add them to your favorite drink. A small sieve works well for rinsing.

Now that you know how to polymerize sodium alginate with calcium, what else could you try? Can you make a foam in the blender? Can you make gummy worms in the bath using the rest of your sodium alginate solution? Can you invent something entirely new??? Try it!

Thank you to Andrew Schloss’s book Amazing (Mostly) Edible Science for the experiment inspiration!  Adding the Kool-Aid and Tang drops to add a little flavor and color was our idea! (This blog post was first published on KitchenPantryScientist.com on May 3rd, 2016 and revised to add popping boba July 24th, 2018.)

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